FRÉDÉRIC SCOTT ARCHER, publica o método da fotografia com colódio.
ON THE USE OF COLLODION IN PHOTOGRAPHY.*
BY FREDERICK SCOTT ARCHER, ESQ.
THE imperfections in paper photography, arising from
the uneven texture of the material, however much care may be taken in the
manufacture of it, and which from its nature, being a fibrous substance,
cannot, I believe, be overcome, has induced me lay it aside and endeavor to
find some other substance more applicable, and meeting the necessary conditions
required of it, such as fineness of surface, transparency, and case of manipulation.
A layer of albumen on glass answers many of these
conditions, producing a fine transparent film, but it is difficult to obtain an
even coating on the glass plate; it requires careful drying, and is so
extremely delicate when damp that it will not bear the slightest handling;
besides these objections, the necessity of having a large stock of glass when a
number of pictures are to be taken, is much against its general use. My
endeavor, therefore, has been to overcome these difficulties, and I find from
numerous trials that Collodion, when
well prepared, is admirably adapted for photographic purposes as a substitute
for paper. It presents a perfecctly transparent and even surface when poured on
glass, and being in some mesure tough and elastic, will, when damp, bear
handling in several stages of the process.
I will now give a short outline of my mode of using
it. The first step in the process is to prepare the solution of collodion.
There are several ways of doing this, but I will briefly allude to two.
Pour a quantity (say 1 oz.) of collodion into a bottle
containing dry iodide of silver. Shake them well together, and then allow the
excess of iodide of silver to settle. The collodion will in this way take up a
certain quantity of the silver salt, and become opaque; it should then be
transferred to another bottle containing iodide of potassium, to be again well
shaken up until the iodide of silver is entirely dissolved, and the solution
becomes perfectly transparent.
Or this: — To a solution of iodide of potassium in
spirits of wine add a small quantity of iodide of silver sufficient to saturate
the iodide of potassium; let, however, the latter salt be in excess. Add a
small quantity of this solution to the collodion, between 5 and 10 grs. by
measure to 1 oz. of collodion will be sufficient, and if any of the iodide of
silver should precipitate, a small quantity of iodide of potassium must be
added to dissolve it. In this way, or by the former mode, the collodion may be
prepared.
The next step is to spread this solution evenly on a
plate of glass. This can be done by pouting a sufficient quantity on the glass
to run in a body freely. When it has entirely covered the glass plate, let the
superabundance be drained off at one corner into the bottle again; this
operation cannot be done too quickly, for the other rapidly evaporating would
prevent the collodion running evenly over the surface of the plate, from
becoming too thick.
The plate is now plunged into a bath of nitrate of
silver, allowed to remain there for a few seconds, and then washed in water.
(This washing is intended to remove all the ether from the surface of the
collodion, which, if allowed to remain, would cause an unevenness in the
sensitiveness of the surface producing streaks or spots.) Immediately after
washing, it made be exposed to the action of light for the time necessary to
obtain a picture. This picture can be developed either by gallic or pyrogallic
acid. If the latter acid be used, a few precautions are necessary, to which I
will allude presently. The former acid may be used as a bath, in the ordinary
way. After the picture is developed, the film of collodion should be loosened
from the edges of the glass plate with a flat glass rod. By doing this, it will
easily separate from the plate and can be allowed to float freely in the water
bath, previous to being placed in the bath of hyposulphite of soda, and then
again thoroughly washed.
The drawing can now be mounted on a plate of glass,
and when dry can be varnished, to protect it from injury.
If thought more convenient (and, in fact, this mode is
the best when pyrogallic acid is used), the film of collodion, after being
exposed to light and the image developed, can be removed from the glass plate
(leaving the fixing and final washing to be done at leisure) by rolling it up
on a glass rod, thus: — Take a sheet of ordinary white wrapping or thick
blotting paper (if glazed it will be better), about the same breadth and about
one-third longer than the drawing to be removed, soak it in water, and place it
with the glazed side in contact with the surface of collodion. Turn the end of
the collodion picture over the edge of the paper lying upon it, then place the
glass rod just within the edge, and commence rolling it upon the rod; with a
little dexterity, this can be accomplished without injuring the drawing. The
cylinder thus formed, is easily removed from the glass rod, and can be
preserved for any length of time in this state by being kept damp and away from
the light, to be finally fixed at some more convenient time. Thus one plate of
glass will be sufficient to make any number of drawings upon, the above
operations being repeated for each picture.
The plate of glass should be rather larger than the drawings intended
to be made upon it, to allow for rough edges, etc. The back of the glass may be
ground to get the focus upon, and one side should be formed into a kind of
handle to prevent the hand of the operator being near the solution when the
glass is in use.
30 grs. of nitrate of silver to 1 oz. of water will be
sufficient for the nitrate of silver bath.
3 grs. of pyrogallic acid to 1 oz. of water, to which
must be added about 1drachm of acetic acid.
Between 5 and 10 grs. of nitrate of silver to 1 oz. of
water.
The two latter solutions are to be mixed in equal
proportions when a picture is to be developed. A wide-mouthed glass measure
will be necessary to hold this mixture.
I have found it convenient to have a trough made of
gutta percha, the two sides and bottom of which are about 1/2 inch high and
just large enough to hold the glass plate. With this trough the mixed solutions
can be poured rapidly over the plate, without fear of any being thrown over the
edges.
18th
February, 1851.
*Communicated
by the Author.
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